Macor-Machinable Glass Ceramic

Strict machining with an accuracy of up to 0.001mm can be achieved

Macor machinable glass ceramic developed by Corning is a high-performance polycrystalline composite material that is white throughout. Its most distinctive feature is that it has zero porosity and zero air leakage. It also has the ability to be processed by standard metal tools and is widely used in high-end manufacturing.

macor

Macor Advantages

  • Easily machinable with standard metalworking tools.
  • Supports extremely tight machining tolerances, up to 0.0005 inches (0.013 mm).
  • Completely non-porous and suitable for vacuum applications without risk of outgassing.
  • No firing is required after machining, simplifying the manufacturing process.
  • High Precision: It allows for high dimensional accuracy and surface finish, making it ideal for applications requiring intricate parts.
  • Macor endures continuous use at temperatures up to 1000°C without degrading, ideal for high-temperature applications
  • Exhibits low thermal conductivity, making it an effective high-temperature insulator.
  • Macor is resistant to most chemicals, including acids, bases, and solvents, making it suitable for harsh chemical environments.
  • Strong and rigid, maintaining its shape without creeping or deforming, unlike high-temperature plastics.
  • Tailored Designs: Macor can be customized to meet specific industrial requirements, offering flexibility in design and application.
  • Material Compatibility: Macor can be easily combined with metals and glass, enhancing its versatility in various applications.

Macor Applications

  • Ultra-high vacuum systems, feedthroughs, and insulators.
  • Semiconductor equipment fixtures, insulators, and precision parts.
  • Mass spectrometers, ion traps, and low-temperature systems.
  • Surgical instruments, diagnostics, and imaging components.
  • Electric insulators in ion thrusters.
  • Electrode holders for plasma generators.
  • Structural supports for high-voltage equipment and transformers.
  • Precision coil formers (stable and high precision).
  • Spacers, cavities, and reflectors in laser assemblies.
  • Satellite system supports (thermally and electronically insulating)

Macor Material Properties

Understanding Macor material properties to help you achieve optimal performance in specific applications

Thermal SI/Metric Imperial
CTE -100°C – 25°C
81 x 10-7/°C
45 x 10-7/°F
CTE 25°C – 300°C
90 x 10-7/°C
50 x 10-7/°F
CTE 25°C – 600°C
112 x 10-7/°C
62 x 10-7/°F
CTE 25°C – 800°C
123 x 10-7/°C
68 x 10-7/°F
Specific Heat, 25°C
0,79 kJ/kg°C
0.19 Btu/lb°F
Thermal Conductivity, 25°C
1,46 W/m°C
10.16 Btu.in/hr.ft²°F
Thermal Diffusivity, 25°C
7,3 x 10-7m²/s
0.028 ft²/hr
Continuous Operating Temperature
800°C
1472°F
Maximum No Load Temperature
1000°C
1832°F

Note: Macor is a machinable ceramic produced by Corning Inc

Mechanical SI/Metric Imperial
Density
2,52 g/cm3
157 lbs/ft3
Porosity
0%
0%
Young’s Modulus, 25°C(Modulus of Elasticity)
66,9 GPa
9.7 x 106 PSI
Poisson’s Ratio
0,29
0,29
Shear Modulus, 25°C
25,5 GPa
3.7 x 106PSI
Knoop Hardness, 100g
250 kg/mm2
——
Modulus of Rupture, 25°C(Flexural Strength)
94 MPa (Minimum specified average value)
13 600 PSI
Compressive Strength(After polishing)
345 MPa(up to 900 MPa)
49 900 PSI(130 000 PSI)
Electrical SI/Metric Imperial
Dielectric Constant, 25°C
——
——
1 kHz
6,01
6,01
8,5 GHz
5,64
5,64
Loss Tangent, 25°C
——
——
1 kHz
0,0040
0,0040
8,5 GHz
0,0025
0,0025
Dielectric Strength (AC) avg. (25°C, under 0,3 mm thickness.)
45 kV/mm
1143 V/mil
Dielectric Strength (DC) avg.(25°C, under 0,3 mm thickness)
129 kV/mm
3277 V/mil
DC Volume Resistivity, 25°C
1017 Ohm.cm
1017 Ohm.cm

Note: This value is for reference only and may vary slightly depending on the batch conditions.

Machining Macor

Although Macor has the ability to process with standard metal tools, there are still some problems compared with metal (please check our latest machining guide for 2025). Ultra-precision machining can be achieved by using alloy milling cutters and correct machining parameters. For example, micro holes can be processed to 0.05mm, and internal threads can reach M1.4, but M1.4 needs to consider its practicality (it is recommended to be larger than M2). In addition, when processing threads, attention should be paid to edge collapse, which is recommended to be solved by chamfering. In terms of cooling, it is recommended to choose water-soluble coolant, which is not easy to adhere to the tool.

Jundro Ceramics is a professional precision manufacturer of Macor Machinable Ceramic materials. We specialize in utilizing our technical expertise and advanced equipment to process high-precision products. Our comprehensive service scope includes material selection, precision machining, surface treatment, and quality testing to ensure that each product can perform at its best in practical applications. If you would like to purchase Macor boards, rods, bars, tubes, or custom machined parts, please contact us

Macor Prototype Machining

Our video showcases the process of prototype machining for Machinable Glass Ceramic

Prototype Machining Case

We specialize in precision machining of Machinable Ceramic with complex shapes, and are able to achieve high-precision machining to meet the needs of various complex designs.

Related Materials and Consultation

High performance machinable aluminum nitride (AIN) ceramics—Shapal HI-M

Advanced material with RoHS certification – Macor Glass Ceramic

Frequently Asked Questions

1.Which material has better heat dissipation?
  • Shapal Hi M Soft has a high thermal conductivity of 90 W/(m · K), making it ideal for applications that require thermal conductivity.
  • Macor is a thermal insulator (1.46 W/(m · K)) that is more suitable for applications that require insulation.
2.How do they perform under rapid temperature changes?
  • Shapal can handle thermal shock well and is reliable for components frequently exposed to heating and cooling cycles.
  • However, in this case, Macor is more prone to cracking.
3.What is their maximum operating temperature?
  • Shapal can withstand temperatures up to 1900 ° C in an inert atmosphere and 1000 ° C in air, making it suitable for extreme environments.
  • Macor has a lower thermal limit, making it more suitable for medium temperature applications.
4.Which material has higher strength?
  • Shapal has higher flexural strength (300 MPa) and compressive strength (1200 MPa), making it ideal for high stress applications.
  • Macor has poor durability, with a bending strength of 94 MPa and a compressive strength of 345 MPa.
5.Is the cost difference significant?
  • Yes, when Macor’s performance meets application requirements, it is more cost-effective and can save a lot of costs.
6.What factors should be considered when making a choice?
  • If your project involves high temperature, mechanical stress, or thermal cycling, Shapal is a better choice.
  • For budget sensitive projects with moderate performance requirements, Macor is a practical alternative.

Macor is a composite material consisting of fluorphlogopite (a type of mica) embedded in a borosilicate glass matrix, with the ratio of mica to glass being approximately 45% and 55%. This structure provides a unique combination of machinability and durability.

2. What are the main chemical components of Macor?

  • The composition of Macor is:
  • 46% Silicon Dioxide (SiO₂)
  • 17% Magnesium Oxide (MgO)
  • 16% Aluminum Oxide (Al₂O₃)
  • 10% Potassium Oxide (K₂O)
  • 7% Boron Oxide (B₂O₃)
  • 4% Fluorine (F)

3. How does its microstructure enhance its machinability?

The random microcrystalline structure of Macor enables precision machining. Tools can remove micron-sized portions of material without causing cracks or breaks, allowing tight tolerances to be achieved.

4. Why does Macor use borosilicate glass?

Borosilicate glass provides thermal stability, chemical resistance, and structural support similar to applications in test tubes and labware such as Pyrex®.

5. What are the advantages of this composition?

The unique combination of mica and borosilicate glass allows Macor to:

  • Be highly processable using standard tools.
  • Be thermally and electrically insulating.
  • Resistant to high temperatures and a wide range of chemical environments.
Corning currently only offers two sizes of Macor materials: 330*350*57mm (approximate size) and φ76mm*317mm. Junjie
The Ceramics Department has extensive experience in the processing of Macor machinable ceramics and can process products in the full range of the above two sizes.
We have 11 high-precision ceramic CNC machining centers and a five-axis machining center. The Macor ceramic products we process include: ion trap lens brackets, quadrupole rods
Ceramic brackets, insulators, etc.
 
  • Processing accuracy
  • Flatness: 0.001mm
  • Dimensional tolerance: 0.001mm
  • Roughness: Ra0.01um

Glass ceramics are materials that combine the properties of glass and ceramics, made by controlled crystallization. Common types include:

1. Mica-based glass ceramics
Example: Macor.
Features: Machinable, electrically insulating, low thermal conductivity.

2. Lithium disilicate glass ceramics
Applications: Dental restorations, optical components.
Features: High strength, good transparency, wear resistance.

3. Aluminosilicate glass ceramics
Applications: Cookware, aviation parts, electronics.
Features: Thermal shock resistance, high temperature resistance.

4. Spinel-based glass ceramics
Applications: Transparent armor, optical devices.
Features: High strength, optical transparency.

5. Apatite-based glass ceramics
Applications: Bioceramics for bone and tooth restorations.
Features: Biocompatibility, bonding to tissues.

6. Zirconia-based glass ceramics
Applications: Crowns, cutting tools.
Features: Tough, wear-resistant, thermally stable.
Glass ceramics are widely used and can be used in aerospace, healthcare, electronics and consumer products.

1. Can Macor be used for prototyping?
Yes, Macor is ideal for prototyping due to its machinability and ability to achieve tight tolerances.

2. What are the benefits of using Macor for prototypes?
Easy machining: Can be shaped quickly with standard tools.
Cost-effective: More affordable than other advanced ceramics.
Fast turnaround: Ideal for rapid iterations and adjustments.

3. What types of prototypes is Macor suitable for?
Macor is great for high-temperature applications, electrical insulation, and mechanical components.

4. Are there any limitations?
Macor may not be suitable for prototypes requiring high mechanical strength or impact resistance.

  1. How to choose tools suitable for Macor ceramic processing?
    When processing Macor, it is recommended to use hard alloy tools as they have good wear resistance and high temperature stability. Using appropriate tools can ensure machining accuracy and surface quality, avoiding premature wear of materials.
  2. What is the best processing method for Macor?
    Macor can be processed through traditional machining methods such as turning, milling, drilling, and grinding. To ensure machining quality, it is recommended to use low-speed cutting and appropriate coolant to reduce thermal stress and material cracking.
  3. How to avoid cracks during the processing?
    Due to Macor being a brittle material, drastic temperature changes should be avoided as much as possible during processing. Using stable cutting parameters and sufficient coolant can reduce thermal stress and avoid cracking.
  4. How to deal with thermal stress during Macor processing?
    During the processing, thermal stress may cause material fracture or deformation. To reduce thermal stress, using sufficient coolant and lower cutting speed while maintaining a stable machining temperature can effectively reduce the impact of thermal stress.
  5. How to ensure the machining accuracy of Macor ceramics?
    The machining accuracy of Macor ceramics can usually reach ± 0.0005 inches (0.013 millimeters). To ensure high-precision machining, high-quality tools should be used and the settings of the machine tool should be strictly controlled to avoid vibration and errors.

Macor is a glass and ceramic material with excellent electrical insulation. Its volume resistivity is generally between 10¹² and 10¹⁴ ohm-cm, which is comparable to alumina and other ceramic materials. It can maintain its insulation properties even under high temperature and high humidity conditions because macor has a non-porous structure and its hygroscopicity is lower than (<0.01%).

Macor has low mass loss in weak acid (such as dilute nitric acid) and neutral salt solution, and its acid resistance level is “4”, which is above average and can meet most industrial needs.
In weak alkaline environment (such as 0.1 N NaOH), the mass loss is greater than that in acidic environment
In strong alkaline environment (such as 5% NaOH, high temperature and high concentration), long-term use will cause Macor to have a significant mass loss of 100 mg/cm² or even more, thus affecting the material mechanics and structural integrity

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